{"id":2266,"date":"2024-08-02T10:08:25","date_gmt":"2024-08-02T02:08:25","guid":{"rendered":"https:\/\/www.bdmaee.cn\/?p=2266"},"modified":"2024-08-02T10:08:25","modified_gmt":"2024-08-02T02:08:25","slug":"crabtree%e5%af%bc%e5%90%91%e6%b0%a2%e5%8c%96%e5%82%ac%e5%8c%96%e5%89%82","status":"publish","type":"post","link":"https:\/\/www.bdmaee.cn\/archives\/2266","title":{"rendered":"Crabtree\u5bfc\u5411\u6c22\u5316\u50ac\u5316\u5242"},"content":{"rendered":"<p>Crabtree\u5bfc\u5411<a href=\"https:\/\/www.pu18.com\/\" target=\"_self\" rel=\"noopener\"><strong>\u6c22\u5316\u50ac\u5316\u5242<\/strong><\/a>\u200b<\/p>\n<p>\u5bfc\u5411\u6027\u70ef\u70c3\u6c22\u5316\u50ac\u5316\u5242\u2014\u2014\u94f1\u50ac\u5316\u5242\uff1a[Ir(cod)(PCy3)pyr]PF6\u6216\u4e0a\u56fe\u7684\u50ac\u5316\u52423 {BArF=\u56db[2,5-\u4e8c(\u4e09\u6c1f\u7532\u6c27\u57fa)\u82ef\u57fa]\u787c}\u3002\u5e38\u89c1\u7684\u5bfc\u5411\u57fa\u56e2\uff1aOH, OMe, C55O, CO2Me, C(O)NR2\u3002\u6b64\u50ac\u5316\u5242\u7531Crabtree RH\u65e9\u57281979\u5e74\u53d1\u73b0\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-2267\" src=\"https:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/08\/1719283971977.png\" width=\"516\" height=\"436\" srcset=\"https:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/08\/1719283971977.png 516w, https:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/08\/1719283971977-300x253.png 300w\" sizes=\"(max-width: 516px) 100vw, 516px\" \/><\/p>\n<p>Roskamp-Feng\u53cd\u5e94<\/p>\n<p>1989\u5e74\uff0cRoskamp\u9996\u5148\u62a5\u9053\u4e86\u5229\u7528\u6c2f\u5316\u4e9a\u9521\u50ac\u5316\u4e59\u57fa\u91cd\u6c2e\u4e59\u9178\u4e59\u916f\u548c\u919b\u53cd\u5e94\u5236\u5907\u03b2-\u916e\u916f\u7684\u53cd\u5e94\u3010J. 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