{"id":2202,"date":"2024-07-16T09:43:33","date_gmt":"2024-07-16T01:43:33","guid":{"rendered":"https:\/\/www.bdmaee.cn\/?p=2202"},"modified":"2024-07-16T09:43:33","modified_gmt":"2024-07-16T01:43:33","slug":"%e6%9c%89%e6%9c%ba%e5%90%88%e6%88%90%e8%af%95%e5%89%82%ef%bc%8827%ef%bc%89-%e8%8b%af%e7%a1%92%e9%94%8c%e5%8d%a4%e5%8c%96%e7%89%a9","status":"publish","type":"post","link":"https:\/\/www.bdmaee.cn\/archives\/2202","title":{"rendered":"\u6709\u673a\u5408\u6210\u8bd5\u5242\uff0827\uff09\u2014\u2014\u82ef\u7852\u950c\u5364\u5316\u7269"},"content":{"rendered":"

\u6709\u673a\u5408\u6210\u8bd5\u5242\uff0827\uff09\u2014\u2014\u82ef\u7852\u950c\u5364\u5316\u7269<\/strong><\/a><\/p>\n

\u7ed3\u6784\u5f0f\uff1a<\/p>\n

\u82f1\u6587\u540d\u5b57\uff1aPhenylselenyl zinc chloride<\/p>\n

\u5206\u5b50\u5f0f\uff1aC6H5ClSeZn<\/p>\n

\u5206\u5b50\u91cf\uff1a140.57<\/p>\n

CAS\u53f7\uff1a\u4e0d\u8be6\uff08\u539f\u6587\u4e2dCAS\u53f75707-04-0\u7ecf\u641c\u7d22\u6307\u793a\u82ef\u57fa\u6c2f\u5316\u7852\uff09<\/p>\n

\u662f\u5426\u5546\u4e1a\u5316\u8bd5\u5242\uff1a\u4e0d\u662f<\/p>\n

<\/p>\n

\u7269\u7406\u6027\u8d28\uff1a\u767d\u8272\u56fa\u4f53\uff0cbp 107~108 \u00b0C \/ 1.0mmHg\u3002\u6613\u6eb6\u4e8e\u7532\u82ef\u3002<\/p>\n

\u5236\u5907\u65b9\u6cd5\uff1a\u53ef\u4ee5\u901a\u8fc7\u5e02\u552e\u7684\u82ef\u7852\u6c2f\u5316\u7269\u5728 THF \u4e2d\u4e0e\u950c\u7c89\u6c27\u5316\u52a0\u6210\u5f97\u5230\u3002<\/p>\n

\u4f7f\u7528\u6ce8\u610f\uff1a\u8be5\u8bd5\u5242\u5177\u6709\u5f3a\u70c8\u7684\u5438\u6e7f\u6027\u3002\u6709\u6bd2\uff0c\u5bf9\u73af\u5883\u6709\u5bb3\uff0c\u4e00\u822c\u5728\u901a\u98ce\u6a71\u4e2d\u8fdb\u884c\u64cd\u4f5c\u3002\u4f4e\u6e29\u50a8\u5b58\u3002<\/p>\n

\u82ef\u7852\u950c\u6c2f\uff08\u6216\u6eb4\uff09\u5316\u7269\u662f\u4e00\u79cd\u7a33\u5b9a\u7684\u542b\u7852\u5316\u5408\u7269[1]\u3002\u4e3b\u8981\u7528\u4f5c\u4eb2\u6838\u8bd5\u5242\u5408\u6210\u542b\u7852\u6709\u673a\u5316\u5408\u7269\u3002\u591a\u4ee5\u6c34\u548cTHF\u505a\u6eb6\u5242\uff0c\u53ef\u4ee5\u4e0e\u542b\u6709\u6613\u79bb\u53bb\u57fa\u56e2\u7684\u5316\u5408\u7269\u53d1\u751f SN2\u53cd\u5e94\uff0c\u5f97\u5230\u76f8\u5e94\u7684\u53d6\u4ee3\u4ea7\u7269 \u3002\u79bb\u53bb\u57fa\u56e2\u79bb\u53bb\u80fd\u529b\u53c2\u8003\uff1a\u6709\u673a\u5408\u6210\u4e2d\u5e38\u89c1\u79bb\u53bb\u57fa\u56e2\u6392\u5e8f\u603b\u7ed3<\/p>\n

<\/p>\n

\u5728 THF\u6216\u6c34\u6eb6\u6db2\u4e2d\uff0c\u4e59\u70ef\u57fa\u5364\u5316\u7269\u53ef\u4ee5\u4e0e\u82ef\u7852\u950c\u5364\u5316\u7269\u8fdb\u884c\u4eb2\u6838\u53d6\u4ee3\u53cd\u5e94\uff0c\u5f97\u5230\u76f8\u5e94\u7684 E-\u6784\u578b\u53d6\u4ee3\u4ea7\u7269\u3002\u5728\u53d6\u4ee3\u53cd\u5e94\u8fc7\u7a0b\u4e2d\u53cd\u5e94\u7269\u7684\u6784\u578b\u4fdd\u6301\u4e0d\u53d8\uff0c\u800c\u4e14\u5728\u6c34\u4ecb\u8d28\u4e2d\u7684\u53cd\u5e94\u6548\u679c\u4f1a\u66f4\u597d\u3002\u4f46\u4f7f\u7528 \u03b2-\u5364\u4ee3-\u03b1,\u03b2-\u4e0d\u9971\u548c\u916e\u4e0e\u82ef\u7852\u950c\u5364\u5316\u7269\u53cd\u5e94\u65f6\uff0c\u7531\u4e8e\u7fb0\u57fa\u4e0e\u950c\u7ed3\u5408\uff0c\u5f97\u5230\u7684\u662fZ-\u6784\u578b\u7684\u4ea7\u7269\u3002<\/p>\n

<\/p>\n

\u6709\u673a\u950c\u8bd5\u5242\u7531\u4e8e\u5176\u826f\u597d\u7684\u5b98\u80fd\u56e2\u8010\u53d7\u6027\u548c\u7a33\u5b9a\u6027\u4ee5\u53ca\u4f4e\u6bd2\u6027\u7684\u7279\u70b9\uff0c\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u78b3\u78b3\u952e\u548c\u78b3\u6742\u539f\u5b50\u952e\u7684\u6784\u5efa\u4e2d\u3002\u867d\u7136\u8fd1\u5e74\u6765\u5f3a\u6709\u529b\u7684\u53cd\u5e94\u53ef\u4ee5\u5229\u7528\u5916\u6d88\u65cb\u8bd5\u5242\u8fdb\u884c\u4e0d\u5bf9\u79f0\u5408\u6210\uff0c\u4f46\u662f\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u8fdb\u4e00\u6b65\u62d3\u5bbd\u4e86\u975e\u5916\u6d88\u65cb\u6709\u673a\u950c\u8bd5\u5242\u7684\u5e94\u7528\u8303\u56f4\u3002\u6700\u5e38\u89c1\u7684\u5236\u5907\u6709\u673a\u950c\u8bd5\u5242\u7684\u65b9\u6cd5\u662f\u950c\u63d2\u5165\u5230\u6709\u673a\u5364\u5316\u7269\u4e2d\uff0c\u4f46\u8fd9\u4e00\u8fc7\u7a0b\u4e00\u822c\u4f1a\u7ecf\u8fc7\u81ea\u7531\u57fa\u4e2d\u95f4\u4f53\uff0c\u8fd9\u4f7f\u5f97\u4e0d\u5bf9\u79f0\u5408\u6210\u5177\u6709\u6311\u6218\u6027\u3002\u5176\u4ed6\u7684\u5236\u5907\u624b\u6027\u6709\u673a\u950c\u8bd5\u5242\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u53d1\u5c55\u3002Knochel\u56e2\u961f\u53d1\u5c55\u4e86\u787c\u6c22\u5316\u548c\u968f\u540e\u7684\u787c-\u950c\u4ea4\u6362\u7b56\u7565\u5f97\u5230\u4e86\u624b\u6027\u6709\u673a\u950c\u8bd5\u5242(\u56fe1a)\uff1bCampos\u901a\u8fc7\u8131\u8d28\u5b50\u5316\/\u8f6c\u91d1\u5c5e\u5316\u7684\u65b9\u6cd5\u5f97\u5230\u4e86\u6742\u73af\u7c7b\u6709\u673a\u950c\u8bd5\u5242(\u56fe1b)\uff0c\u8be5\u7b56\u7565\u540e\u6765\u88abGawley\u4fee\u6539\u4e3a\u4f7f\u7528\u50ac\u5316\u91cf\u7684\u9502\u5316\u4e8c\u6c28\u57fa\u9187\u76d0(\u56fe1c)\uff1b\u8fd1\u671f\uff0cKnochel\u56e2\u961f\u901a\u8fc7\u9502-\u5364\u7d20\u539f\u5b50\u4ea4\u6362\u4ee5\u53ca\u968f\u540e\u7684\u8f6c\u91d1\u5c5e\u5316\u5f97\u5230\u4e86\u624b\u6027\u4e8c\u70f7\u57fa\u950c\u8bd5\u5242(\u56fe1d)\u3002\u03c0-\u952e\u7684\u76f4\u63a5\u78b3\u950c\u5316\u662f\u5f88\u7279\u522b\u7684\u65b9\u6cd5\u4e4b\u4e00\uff0c\u4f46\u662f\u88ab\u62a5\u9053\u5f97\u5f88\u5c11\uff0c\u5e76\u4e14\u4ec5\u6709\u5177\u6709\u5e94\u529b\u548c\u6d3b\u5316\u7684\u70ef\u70c3\u53ef\u4ee5\u5b9e\u73b0(\u56fe1e)\u3002\u672c\u6587\uff0c\u6ce2\u58eb\u987f\u5b66\u9662\u7684JamesP. Morken\u53d1\u5c55\u4e86\u624b\u6027\u954d\u50ac\u5316\u5242\u53c2\u4e0e\u7684\u4e59\u70ef\u57fa\u787c\u9178\u916f\u7684\u78b3\u950c\u5316\uff0c\u5f97\u5230\u624b\u6027\u03b1-\u787c\u950c\u8bd5\u5242\uff0c\u8be5\u4ea7\u7269\u6784\u578b\u7a33\u5b9a\u53ef\u4e0e\u591a\u79cd\u4eb2\u7535\u8bd5\u5242\u53cd\u5e94\u5f97\u5230\u624b\u6027\u70f7\u57fa\u787c\u9178\u916f<\/p>\n","protected":false},"excerpt":{"rendered":"

\u6709\u673a\u5408\u6210\u8bd5\u5242\uff0827\uff09\u2014\u2014\u82ef\u7852\u950c\u5364\u5316\u7269 \u7ed3\u6784\u5f0f\uff1a \u82f1\u6587\u540d\u5b57\uff1aPhenylselenyl zinc chloride \u5206\u5b50\u5f0f\uff1aC6H5ClSeZ… <\/p>\n","protected":false},"author":2,"featured_media":2203,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-2202","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news"],"_links":{"self":[{"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2202"}],"collection":[{"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/comments?post=2202"}],"version-history":[{"count":1,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2202\/revisions"}],"predecessor-version":[{"id":2206,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2202\/revisions\/2206"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media\/2203"}],"wp:attachment":[{"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media?parent=2202"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/categories?post=2202"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/tags?post=2202"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}